Change default 15 products per page on Category view
Goto Extensions in Extensions in opencart, Choose the extension type Theme
Click on edit button and change below listed value
For views change value from category.php from controller directory
$data['limits'] = array();
$limits = array_unique(array($this->config->get('theme_' . $this->config->get('config_theme') . '_product_limit'), 25, 50, 75, 100));
sort($limits);